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Solubility
of Hardness Salts
The
solubility of a salt varies with the temperature. The solubility, e.g.
of sugar goes up with a rise in temp. Conversely, the solubility of CaCO3
goes down with temperature rise. There is no general rule; each and every
compound has to be checked in a Physical Chemistry Table for solubility.
In practice, sulphates and carbonates decrease the solubility with temperature;
everything else increases. Let us therefore take the example of CaCO3
in a heat exchanger. The increase in temperature causes the salt, of a
part of it, to precipitate out.
When
the temperature in the fig. shifts from T1 to T2 the solubility of CaCO3
drops from S1 an S2 and the amount of precipitation
becomes S1-S2. Place a Scale-Ban upstream of a Heat Exchanger and
it will precipitate out most of the CaCO3 before it goes into the Heat
Exchanger. If it precipitates out from S1 to S3, then the temperature
change from T1 to T2 will not cause scaling. If it precipitates out only
to S4, then the temperature change T1 to T2 will cause a little scaling
(from S4 to S2). T1 to T3 would cause more (S4 to S3) etc.
The characteristic curves for each salt are going to be different and
they themselves are going to be altered by the presence of other salts.
This makes the whole thing much more complicated, in practice, than in
this simplified explanation.
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SCALE
AND ITS EFFECT
Insulating properties of scale :
Scale
formation is a common phenomenon in any industry using water as
a coolant or for steam generation. Scale has insulation properties,
thus resulting in bad heat transfer (see graph). Apart from a drop
in efficiency, the effect is overheating of machines, and frequent
breakdowns because of equipment choking. The cleaning process is
recurring and it reduces the life of the machines
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| ADVANTAGES
OF SCALE- BAN |
- Prevention
of Scale
Due to its unique ability to precipitate
dissolved solids into a colloidal suspension, scale tends
to build up on these seed crystals rather than on the heat
transfer areas, thereby preventing the deposition of scale
on the transfer areas.
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- Removal
of existing Scale
The reduction of the free calcium
from solution by the formation of these calcium carbonate
crystals, and the solubility being constant, water can dissolve
more salts, which it tends to pick up from the existing
scale in the system thereby desalting scaled up systems
under ideal conditions. However as the solubility is affected
by the changes in pH, temperature and pressure, Scale-Ban
will descale only in ideal conditions of above parameters.
Hence it is not marketed as a scale remover, but as a scale
preventor.
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- Eliminates
Recurring Cost, Expensive Chemicals, Regenerative Salts,
Resins & Electricity
The Scale-Ban has no recurring
cots as associated with Chemical Dosing or Water Softening,
as no chemicals, regenerative salts or resins are used.
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- Chemical
Composition of the Water does not change
The Scale-Ban does
not change the chemical composition of water, but instead,
changes the physical composition of the scaling salts from
a dissolved state to a suspended state, thereby preventing
scale build up. The Chemistry of the water, being the same,
can be used in the process itself, for example as in beer
making.
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- No
Corrosion Risk
Water softeners necessitate the of
corrosion inhibitors, as the water tends to be corrosive.
Similarly, Chemical Dosing reduces the pH of water, thereby
increasing the risk of corrosion. Scale-Ban on the
other hand, has the unique advantage of preventing scale
deposition without increasing the risk of corrosion .
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- Eliminates
recurring Labour Costs
The Scale-Ban is a fit-and-forget
system. It does not require any labour, or supervision for
chemical addition or for regeneration salts as required
for Chemical Dosing and Water Softener.
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- Requires
no Maintenance
The Scale-Ban has no moving
parts, it requires no replacement of parts or maintenance,
other than normal plant maintenance.
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- Save
Fuel consumption
Scale reduces heat transfer efficiency
resulting in increased energy use which can rise by almost
50%. In AC System, a 5mm fouling of the condensers can result
in an increase of power costs by over 30%. As the Scale-Ban
is fitted on line, it is constantly preventing the deposition
of scale, thereby saving valuable energy costs as compared
to manual desalting systems, which require desalting to
the done periodically.
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- No
Energy Consumption
Unlike conventional water treatment
systems, Scale-Ban does not require any power or
electrical inputs.
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- No
Pollution
Chemical Dosing and Water Softening
Systems necessitate the use of Chemicals which are hazardous
and cause pollution, and hence have to be treated before
water is released into the under-ground water table. The
Scale-Ban, on the other hand, does not require the
use of any chemicals.
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- Scale-Ban
can Handle Variable Water Qualities
In conventional systems of Chemical
Dosing and Water softening, the quantity of Chemicals have
to be adjusted to the water quality, hence the system has
to be closely monitored for variable water qualities. Scale-Ban,
on the other hand, is not affected by variable water qualities
and can handle water up to any hardness.
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- No
Investment Risk
The Scale-Ban is sold with
a one year guarantee. In view of this there is no investment
risk on the part of the user of the equipment
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